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Chlorates and perchlorates are fairly unstable, and readily decompose into chlorides + oxygen gas when heated. Could we solve two problems at once by washing the perchlorates out of the soil, and then decomposing them to produce oxygen for breathing and propellant?
Sure, just gotta dig 11.5 to 20 km down to get to some water. Or melt the ice caps, which probably already have the perchlorates frozen in them.