I'm quite fond of "A Christmas Carol" done with flying sharks.
I adore Nick Frost as Santa Clause deriding the Doctor for not believing in a magical man who always has a big adventure at Christmas. And overall, it's just a fantastic episode of Doctor Who.
But yes, The Husbands of River Song probably tops the list. There's scenes that call for action, drama, comedy and tears, and Alex Kingston delivers it all in spades.